Distortion-driven spin switching in electron-doped metal porphyrins
نویسندگان
چکیده
Different conformers can be stabilized for flexible porphyrins upon electron doping. The metastable flat conformer relaxes to the energetically favored distorted form, inducing spin switching in chelated nickel ion.
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ژورنال
عنوان ژورنال: Journal of Materials Chemistry C
سال: 2022
ISSN: ['2050-7526', '2050-7534']
DOI: https://doi.org/10.1039/d2tc01253g